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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

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Manganese(III)-Promoted Tandem Oxidation and Cyclization of beta-Keto Ester Derivatives of Terpenoids

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Title
Manganese(III)-Promoted Tandem Oxidation and Cyclization of beta-Keto Ester Derivatives of Terpenoids
Author
Li, ZhilongJung, HeejungPark, MiraLah, Myoung SooKoo, Sangho
Issue Date
2011-08
Publisher
WILEY-BLACKWELL
Citation
ADVANCED SYNTHESIS & CATALYSIS, v.353, no.11-12, pp.1913 - 1917
Abstract
A new type of terpenoid cyclization directed by a beta-keto ester moiety has been developed, which proceeded by manganese(III)-initiated oxidation of the beta-keto ester, followed by an intramolecular hetero Diels-Alder reaction with the terpenoid chain. This reaction produces polycyclic dihydropyrans in high yields and stereoselectivities under mild conditions.
URI
https://scholarworks.unist.ac.kr/handle/201301/3536
URL
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=80051987330
DOI
10.1002/adsc.201100215
ISSN
1615-4150
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CHM_Journal Papers
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