This Letter describes dynamic self-assembly in a system of stainless steel spheres (similar to1 mm in diameter) rolling on a flat dielectric surface under the influence of an external magnetic field that rotates parallel to the plane of the surface. As the spheres move, they charge triboelectrically. Self-assembly is mediated by two types of electrostatic interactions among these charges: (i) attraction between negatively charged regions of the surface and positively charged spheres and (ii) repulsion between the like-charged spheres. The spheres organize into highly ordered rings as a result of these electrostatic interactions.