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- Bielawski, Christopher W.
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Synthesis and study of the first n-aryl acyclic diaminocarbene and its transition-metal complexes
- Author(s)
- Rosen, Evelyn L., Sanderson, Matthew D., Saravanakumar, Shanmuganathan, Bielawski, Christopher W.
- Issued Date
- 2007-11
- Citation
- ORGANOMETALLICS, v.26, no.24, pp.5774 - 5777
- Abstract
- The first acyclic diaminocarbene (ADC) featuring N-aryl groups, as well as two complexes containing this ligand, (ADC)RhCl(1,5-cis,cis-cyclooctadiene) and (ADC)RhCl(CO)(2), were synthesized and characterized. Insight into controlling conformational diversity in acyclic diaminocarbenes with N-aryl groups through judicious N substitution was also explored.
- Publisher
- AMER CHEMICAL SOC
- ISSN
- 0276-7333
- Keyword
- HETEROCYCLIC CARBENES, LIGANDS, DIMERIZATION, SALTS
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