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BielawskiChristopher W

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Diaminocarbene[3]ferrocenophanes and their transition-metal complexes

Author(s)
Khramov, Dimitri M.Rosen, Evelyn L.Lynch, Vincent M.Bielawski, Christopher W.
Issued Date
2008-03
DOI
10.1002/anie.200704978
URI
https://scholarworks.unist.ac.kr/handle/201301/33285
Fulltext
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.200704978
Citation
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.47, no.12, pp.2267 - 2270
Abstract
Jones'n for electrons : Various Rh complexes (see general structure) were formed with diaminocarbenes that contain 1,1′‐disubstituted ferrocenes in their backbones. Electronic communication between the Fe centers in the redox‐active carbenes and the coordinated transition metals was observed. For example, the oxidation potential of the Fe center in a bimetallic complex was found to depend on the electron density of the ligated Rh atom.
Publisher
WILEY-V C H VERLAG GMBH
ISSN
1433-7851
Keyword (Author)
bimetallic complexescarbeneselectrochemistryferroceneredox-active ligands
Keyword
N-HETEROCYCLIC CARBENELIGANDSREACTIVITYMOSSBAUERCYCLOPENTADIENYLDIAMINOCARBENESCOMMUNICATIONMETALLOCENESFERROCENECHELATE

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