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BielawskiChristopher W

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Adapting N-Heterocyclic Carbene/Azide Coupling Chemistry for Polymer Synthesis: Enabling Access to Aromatic Polytriazenes

Author(s)
Coady, Daniel J.Khramov, Dimitri M.Norris, Brent C.Tennyson, Andrew G.Bielawski, Christopher W.
Issued Date
2009
DOI
10.1002/anie.200901046
URI
https://scholarworks.unist.ac.kr/handle/201301/33276
Fulltext
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.200901046
Citation
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.48, no.28, pp.5187 - 5190
Abstract
Coupling bis(N‐heterocyclic carbene)s with bis(azide)s afforded a novel class of conjugated polytriazenes. These polymers were rendered electrically conductive upon doping, and fluorene‐containing variants exhibited luminescence. This adaptation of N‐heterocyclic carbene (NHC)/azide coupling chemistry to polymer synthesis reveals the potential of NHCs as building blocks for accessing polymers having useful electronic properties.
Publisher
WILEY-V C H VERLAG GMBH
ISSN
1433-7851
Keyword (Author)
azidescarbenesclick chemistrycoupling reactionspolymers
Keyword
AZA-WITTIG POLYMERIZATIONCLICK-CHEMISTRYTHIN-FILMSELECTRONIC-STRUCTUREPOLYAZOMETHINESAZIDESETHERPOLY(AZOMETHINE)POLYAZINESTRIAZENES

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