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BielawskiChristopher W

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Electropolymerization of an N-Heterocyclic Carbene-Gold(I) Complex

Author(s)
Powell, Adam B.Bielawski, Christopher W.Cowley, Alan H.
Issued Date
2009-12
DOI
10.1021/ja908969q
URI
https://scholarworks.unist.ac.kr/handle/201301/33268
Fulltext
https://pubs.acs.org/doi/10.1021/ja908969q
Citation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.131, no.51, pp.18232 - +
Abstract
We report the first example of a polymer in which each monomer contains an N-heterocyclic carbene (NHC) orthogonally connected to its main chain. A polymerizable imidazolylidene-AuCl complex containing pendant bithiophene moieties was prepared in a high-yield multistep procedure. Oxidative electropolymerization of this monomer afforded the desired polymer, (Au[NHC]Cl)(n), which was characterized via electrochemical studies as well as X-ray photoelectron and UV-vis spectroscopy.
Publisher
AMER CHEMICAL SOC
ISSN
0002-7863
Keyword
CHAIN ORGANOMETALLIC POLYMERSSTRUCTURAL-CHARACTERIZATIONCARBENE COMPLEXESGOLD(I) COMPLEXESMETAL-COMPLEXESCATALYSISDESIGNLIGAND

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