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- Bielawski, Christopher W.
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SYNTHESIS, STUDY, AND APPLICATIONS OF POLYMERIC N-HETEROCYCLIC CARBENES
- Author(s)
- Powell, Adam B., Bielawski, Christopher W., Cowley, Alan H.
- Issued Date
- 2010
- Citation
- COMMENTS ON INORGANIC CHEMISTRY, v.31, no.3-4, pp.75 - 82
- Abstract
- A brief review of our work on orthogonally-positioned NHC metallopolymers is highlighted herein. Some pertinent literature is presented, followed by the synthetic strategy employed as well as comprehensive electrochemical analyses. Derivatization of a suitable diimine into a electropolymerizable gold (I) NHC complex resulted in the first orthogonally-positioned NHC metallopolymer. Extension of this methodology to prepare analogous group 11, iridium and sulfur-substituted metallopolymers generated thin films with electrochromic activity that could be tuned by proper selection of the metal center.
- Publisher
- TAYLOR & FRANCIS LTD
- ISSN
- 0260-3594
- Keyword (Author)
- electrochromism, electropolymerization, metallopolymer, N-heterocyclic carbene
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