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- Bielawski, Christopher W.
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N,N '-Diamidoketenimines via Coupling of Isocyanides to an N-Heterocyclic Carbene
- Issued Date
- 2010-04
- Citation
- JOURNAL OF ORGANIC CHEMISTRY, v.75, no.8, pp.2763 - 2766
- Abstract
- Treatment of an N-heterocyclic carbene that features two amide groups N-bound to the carbene nucleus with various organic isocyanides afforded a new class of ketenimines in yields of up to 96% (isolated). DFT analyses revealed that the carbene exhibits a unique, low-lying LUMO, which may explain the atypical reactivity observed.
- Publisher
- AMER CHEMICAL SOC
- ISSN
- 0022-3263
- Keyword
- STABLE CARBENES, DIMERIZATION, STABILITY, CHEMISTRY
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