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- Bielawski, Christopher W.
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Structurally Characterized Cationic Silver(I) and Ruthenium(II) Carbene Complexes of 1,2,3-Triazol-5-ylidenes
- Author(s)
- Cai, Jiajia, Yang, Xiaoping, Arumugam, Kuppuswamy, Bielawski, Christopher W., Sessler, Jonathan L.
- Issued Date
- 2011-09
- Citation
- ORGANOMETALLICS, v.30, no.18, pp.5033 - 5037
- Abstract
- A novel 1,3,4-substituted 1,2,3-triazolium salt was found to function as an effective precursor for the synthesis of the first structurally characterized cationic silver(I) and ruthenium(II) carbene complexes of overall 1:2 ligand-to-metal stoichiometry. The Ag(I) complex crystallized in the form of an eight silver atom containing cluster, whereas the Ru(II) complex proved to be a discrete species and was found to be capable of initiating the ring-opening metathesis polymerization of norbornene upon activation with (trimethylsilyl)diazomethane.
- Publisher
- AMER CHEMICAL SOC
- ISSN
- 0276-7333
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