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- Grzybowski, Bartosz A.
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A Metal-Organic Framework Stabilizes an Occluded Photocatalyst
- Author(s)
- Han, Shuangbing, Wei, Yanhu, Grzybowski, Bartosz A.
- Issued Date
- 2013-08
- Citation
- CHEMISTRY-A EUROPEAN JOURNAL, v.19, no.34, pp.11194 - 11198
- Abstract
- Occlusion and confinement of a [Ru(bpy)3]Cl2 photocatalyst in the cavities of a γ‐cyclodextrin (CD) metal–organic framework (MOF) does not affect the catalyst's activity but prevents its photodegradation. Additionally, the OH− ions and/or ROH groups present inside the CD‐MOF act as electron donors and complete the catalytic cycle. The occlusion approach is a technically straightforward alternative to the covalent modification of MOF scaffolds with catalytic units.
- Publisher
- WILEY-V C H VERLAG GMBH
- ISSN
- 0947-6539
- Keyword (Author)
- metal-organic frameworks, nanoparticles, photocatalysts, ruthenium
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