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- Bielawski, Christopher W.
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Highly efficient ring-opening metathesis polymerization (ROMP) using new ruthenium catalysts containing N-heterocyclic carbene ligands
- Author(s)
- Bielawski, CW, Grubbs, RH
- Issued Date
- 2000
- Citation
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.39, no.16, pp.2903 - 2906
- Abstract
- Up to one hundred thousand equivalents of a variety of low‐strain cyclic olefins, such as cyclooctadiene, cyclooctene, and several functionalized and sterically hindered derivatives, were polymerized by using highly active ruthenium‐based ring‐opening metathesis polymerization (ROMP) catalysts [Eq. (1)]. Efficient syntheses of other polymeric structures were also accomplished.
- Publisher
- WILEY-V C H VERLAG GMBH
- ISSN
- 1433-7851
- Keyword (Author)
- carbenes, metathesis, polymerizations, ruthenium
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