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Synthesis and study of Janus bis(carbene)s and their transition-metal complexes

Author(s)
Khramov, Dimitri M., Boydston, Andrew J., Bielawski, Christopher W.
Issued Date
2006-09
DOI
10.1002/anie.200601583
URI
https://scholarworks.unist.ac.kr/handle/201301/33054
Fulltext
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.200601583
Citation
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.45, no.37, pp.6186 - 6189
Abstract
Deuces wild : From catalysis through materials science to biology, N‐heterocyclic carbenes (NHCs) can truly be regarded as a wild card of ligands. A new series of “two‐faced” (Janus‐type) ligands composed of two linearly opposed NHCs fused to an arene linker has been synthesized and can be used to prepare discrete bimetallic complexes.
Publisher
WILEY-V C H VERLAG GMBH
ISSN
1433-7851
Keyword (Author)
azolium salts, carbene ligands, heterometallic complexes, organic-inorganic hybrid composites, transition metals
Keyword
N-HETEROCYCLIC CARBENE, BENZOBIS(IMIDAZOLIUM) SALTS, STABLE CARBENES, LIGANDS, GENERATION, CHEMISTRY, PALLADIUM, CATALYSIS, POLYMERS, SEQUENCE

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