Two-dimensional amine and hydroxy functionalized fused aromatic covalent organic framework
Cited 0 times inCited 0 times in
- Two-dimensional amine and hydroxy functionalized fused aromatic covalent organic framework
- Mahmood, Javeed; Ahmad, Ishfaq; Jung, Minbok; Seo, Jeong-Min; Yu, Soo-Young; Noh, Hyuk-Jun; Kim, Young Hyun; Shin, Hyung-Joon; Baek, Jong-Beom
- Issue Date
- NATURE PUBLISHING GROUP
- COMMUNICATIONS CHEMISTRY, v.3
- Ordered two-dimensional covalent organic frameworks (COFs) have generally been synthesized using reversible reactions. It has been difficult to synthesize a similar degree of ordered COFs using irreversible reactions. Developing COFs with a fused aromatic ring system via an irreversible reaction is highly desirable but has remained a significant challenge. Here we demonstrate a COF that can be synthesized from organic building blocks via irreversible condensation (aromatization). The as-synthesized robust fused aromatic COF (F-COF) exhibits high crystallinity. Its lattice structure is characterized by scanning tunneling microscopy and X-ray diffraction pattern. Because of its fused aromatic ring system, the F-COF structure possesses high physiochemical stability, due to the absence of hydrolysable weak covalent bonds.
- Appears in Collections:
- MSE_Journal Papers
- Files in This Item:
Two-dimensional amine and hydroxy functionalized fused aromatic covalent organic framework.pdf
can give you direct access to the published full text of this article. (UNISTARs only)
Show full item record
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.