File Download
There are no files associated with this item.
SFX Link
- Find it @ UNIST can give you direct access to the published full text of this article. (UNISTARs only)
- Bielawski, Christopher W.
Views & Downloads
Detailed Information
Cited time in 
Cited time in 
Cited time in
Metadata Downloads
Reductive generation of stable, five-membered N,N '-diamidocarbenes
- Author(s)
- Moerdyk, Jonathan P., Bielawski, Christopher W.
- Issued Date
- 2014
- Citation
- CHEMICAL COMMUNICATIONS, v.50, no.35, pp.4551 - 4553
- Abstract
- The synthesis of the first stable, five-membered N,N'-diamidocarbenes (DACs), including a differentially N-substituted derivative, was achieved via the reduction of a geminal dichloride precursor using potassium. Key differences between the reactivity of the five-membered DACs and their six-membered congeners were observed, including an ability to insert into electron-rich C-H bonds.
- Publisher
- ROYAL SOC CHEMISTRY
- ISSN
- 1359-7345
- Keyword
- N-HETEROCYCLIC CARBENES, ACTIVATION, AMMONIA, AMINO, COMPLEXES, BACKBONE, PRECURSORS, REACTIVITY, VERSATILE, ALKYL
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.