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김희령

Kim, Hee Reyoung
RAdiation and MagnetohydroDynamics Advanced Lab.
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Detection of tritium generated by proton exchange membrane electrolysis by optimization of electrolysis conditions

Author(s)
Kang, KijoonBae, Jun WooKim, Hee Reyoung
Issued Date
2019-12
DOI
10.1007/s10967-019-06771-8
URI
https://scholarworks.unist.ac.kr/handle/201301/30601
Fulltext
https://link.springer.com/article/10.1007%2Fs10967-019-06771-8
Citation
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, v.322, no.3, pp.1417 - 1421
Abstract
The electrolysis conditions in a proton exchange membrane (PEM) cell were optimized by varying the current supplied; the detection efficiency for gaseous tritium generated from the PEM cell under optimized electrolysis conditions was analyzed. The current was optimized to 7A. Under the optimized current condition, the change in activity of the tritiated water before and after electrolysis was 200 ± 11kBq. When tritiated water with tritium activity concentration of 2912kBq/L was electrolyzed, the detection efficiency was 31.3 ± 1.3%. Moreover, the minimum detectable activity of gaseous tritium was 10.3 ± 0.8kBq/m3 in 5min.
Publisher
SPRINGER
ISSN
0236-5731
Keyword (Author)
Current optimizationElectrolysisProton exchange membraneTritium detection
Keyword
WATER

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