Order-of-Magnitude, Broadband-Enhanced Light Emission from Quantum Dots Assembled in Multiscale Phase-Separated Block Copolymers
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- Order-of-Magnitude, Broadband-Enhanced Light Emission from Quantum Dots Assembled in Multiscale Phase-Separated Block Copolymers
- Kim, Geon Yeong; Kim, Shinho; Choi, Jinyoung; Kim, Moohyun; Lim, Hunhee; Nam, Tae Won; Choi, Wonseok; Cho, Euene N.; Han, Hyeuk Jin; Lee, ChulHee; Kim, Jong Chan; Jeong, Hu Young; Choi, Sung-Yool; Jang, Min Seok; Jeon, Duk Young; Jung, Yeon Sik
- Issue Date
- AMER CHEMICAL SOC
- NANO LETTERS, v.19, no.10, pp.6827 - 6838
- Achieving high emission efficiency in solid-state quantum dots (QDs) is an essential requirement for high-performance QD optoelectronics. However, most QD films suffer from insufficient excitation and light extraction efficiencies, along with nonradiative energy transfer between closely adjacent QDs. Herein, we suggest a highly effective strategy to enhance the photoluminescence (PL) of QD composite films through an assembly of QDs and poly-(styrene-b-4-vinylpyridine)) (PS-b-P4VP) block copolymer (BCP). A BCP matrix casted under controlled humidity provides multiscale phase-separation features based on (1) submicrometer-scale spinodal decomposition between polymer-rich and water-rich phases and (2) sub-10 nm-scale microphase separation between polymer blocks. The BCP-QD composite containing bicontinuous random pores achieves significant enhancement of both light absorption and extraction efficiencies via effective random light scattering. Moreover, the microphase-separated morphology substantially reduces the Forster resonance energy transfer efficiency from 53% (pure QD film) to 22% (BCP-QD composite), collectively achieving an unprecedented 21-fold enhanced PL over a broad spectral range.
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