Synthesis of metallic ReO3 nanowires
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- Synthesis of metallic ReO3 nanowires
- Myung, Dongshin; Lee, Yumin; Lee, Jaeyeon; Yu, Hak Ki; Lee, Jong-Lam; Baik, Jeong Min; Kim, Woong; Kim, Myung Hwa
- Cubic perovskite; Disordered structures; Hydrogen intercalation; Metallic; Metallic rhenium; Near-surface layers; Physical vapor transport; Powder precursors; Raman measurements; ReO3; Rhenium trioxide; Simple cubic; Single-crystalline; XRD
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- PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, v.4, no.12, pp.365 - 367
- We present the synthesis of highly crystalline metallic rhenium trioxide (ReO3) nanowires via a simple physical vapor transport at 300 degrees C for the first time. Based on HIRTFM, the ReO3 nanowires exhibit a core of perfect cubic perovskite-type single crystal structure with a shell of thin amorphous and disordered structures of less than 2 nm in the near surface layers. Possibly this is due to proton interealation induced by the surface reaction of single crystal ReO3 with water.
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