Stable Aqueous Dispersion of Reduced Graphene Nanosheets via Non-Covalent Functionalization with Conducting Polymers and Application in Transparent Electrodes
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- Stable Aqueous Dispersion of Reduced Graphene Nanosheets via Non-Covalent Functionalization with Conducting Polymers and Application in Transparent Electrodes
- Jo, Kiyoung; Lee, Taemin; Choi, Hyun Jung; Park, Ju Hyun; Lee, Dong Jun; Lee, Dong Wook; Kim, Byeong-Su
- Additional flexibilities; Aqueous dispersions; Aqueous suspensions; Chemical reduction; Colloidal Stability; Cooperative interactions; Electrostatic repulsion; Facile method; Graphene sheets; High conductivity; Hybrid film; Hybrid nanocomposites; Network structures; Non-covalent functionalization; PEDOT:PSS; Poly(styrene sulfonate); Potential applications; Transparent electrode
- Issue Date
- AMER CHEMICAL SOC
- LANGMUIR, v.27, no.5, pp.2014 - 2018
- We developed a simple and facile method of producing a stable aqueous suspension of reduced graphene oxide (RGO) nanosheets through the chemical reduction of graphene oxide in the presence of a conducting polymer dispersant, poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) (PEDOT:PSS). This approach involves the cooperative interactions of strong pi-pi interactions between a two-dimensional graphene sheet and a rigid backbone of PEDOT and the intermolecular electrostatic repulsions between negatively charged PSS bound on the RGO sheets, which impart the colloidal stability of the resulting hybrid nanocomposite of RGO/PEDOT. Moreover, our one-step solution-based method allows preserving the intrinsic chemical and electronic properties of both components, yielding a hybrid film of RGO nanosheets of high conductivity of 2.3 k Omega/sq with a transmittance of 80%. By taking advantage of conducting network structure of conducting polymers which provides an additional flexibility and mechanical stability of RGO nanosheets, we demonstrate the potential application of hybrid RGO/PEDOT as highly flexible and transparent electrodes.
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