Ultrahigh-current-density niobium disulfide catalysts for hydrogen evolution
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- Ultrahigh-current-density niobium disulfide catalysts for hydrogen evolution
- Yang, Jieun; Mohmad, Abdul Rahman; Wang, Yan; Fullon, Raymond; Song, Xiuju; Zhao, Fang; Bozkurt, Ibrahim; Augustin, Mathias; Santos, Elton J. G.; Shin, Hyeon Suk; Zhang, Wenjing; Voiry, Damien; Jeong, Hu Young; Chhowalla, Manish
- Issue Date
- Nature Publishing Group
- NATURE MATERIALS, v.18, no.12, pp.1309 - 1314
- Metallic transition metal dichalcogenides (TMDs)1–8 are good catalysts for the hydrogen evolution reaction (HER). The overpotential and Tafel slope values of metallic phases and edges9 of two-dimensional (2D) TMDs approach those of Pt. However, the overall current density of 2D TMD catalysts remains orders of magnitude lower (~10–100 mA cm−2) than industrial Pt and Ir electrolysers (>1,000 mA cm−2)10,11. Here, we report the synthesis of the metallic 2H phase of niobium disulfide with additional niobium (2H Nb1+xS2, where x is ~0.35)12 as a HER catalyst with current densities of >5,000 mA cm−2 at ~420 mV versus a reversible hydrogen electrode. We find the exchange current density at 0 V for 2H Nb1.35S2 to be ~0.8 mA cm−2, corresponding to a turnover frequency of ~0.2 s−1. We demonstrate an electrolyser based on a 2H Nb1+ xS2 cathode that can generate current densities of 1,000 mA cm−2. Our theoretical results reveal that 2H Nb1+ xS2 with Nb-terminated surface has free energy for hydrogen adsorption that is close to thermoneutral, facilitating HER. Therefore, 2H Nb1+ xS2 could be a viable catalyst for practical electrolysers.
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