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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)

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Self-Assembly of Cationic, Hetero- or Homonuclear Ruthenium(II) Macrocyclic Rectangles and Their Photophysical, Electrochemical, and Biological Studies

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Title
Self-Assembly of Cationic, Hetero- or Homonuclear Ruthenium(II) Macrocyclic Rectangles and Their Photophysical, Electrochemical, and Biological Studies
Author
Vajpayee, VaishaliSong, Young HoYang, Yoon JungKang, Se ChanCook, Timothy R.Kim, Dong WookLah, Myoung SooKim, In SuWang, MingStang, Peter J.Chi, Ki-Whan
Keywords
Anti-tumor activities; Biological studies; Coordination-driven; Fluorescence studies; Homonuclear; Human cancer cells; Macrocyclics; Molecular clips; Multinuclear NMR; Photophysical; Rectangular structure; Redox behavior; Two-component; X-ray diffraction studies
Issue Date
201112
Publisher
AMER CHEMICAL SOC
Citation
ORGANOMETALLICS, v.30, no.23, pp.6482 - 6489
Abstract
A series of supramolecular rectangles, including two mixed-metal Ru/Pt complexes, have been formed by the coordination-driven self-assembly of a range of arene-Ru "molecular clip" acceptors (la id) with rigid dipyridyl-based ligands (2a-2d) over the course of 10 h in solution. The isolated products were characterized by multinuclear NMR ((1)H and (13)C or (31)P), HR-ESI-MS, and an X-ray diffraction study to support the ascribed two-component rectangular structures. The rectangles were further characterized by UV-vis and fluorescence studies. The redox behaviors of rectangles 3ca and 3da were also determined using cyclic voltammetry. Additionally, the antitumor activities of the suite of rectangles were determined against various human cancer cell lines, and significant activity was shown by complexes 3ca, 3da, 3cb, 3cc, and 3cd, with IC(50) values as low as 2.65 mu M.
URI
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DOI
http://dx.doi.org/10.1021/om200908c
ISSN
0276-7333
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