3,6-Connected Metal-Organic Frameworks Based on Triscarboxylate as a 3-Connected Organic Node and a Linear Trinuclear Co-3(COO)(6) Secondary Building Unit as a 6-Connected Node
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- 3,6-Connected Metal-Organic Frameworks Based on Triscarboxylate as a 3-Connected Organic Node and a Linear Trinuclear Co-3(COO)(6) Secondary Building Unit as a 6-Connected Node
- Lah, Myoung Soo; Kim, Dongwook; Song, Xiaokai; Yoon, Jung Hee
- Cobalt chlorides; Dimethylacetamide; Inversion point; Layered Structures; Metal organic framework; Net topology; Point symmetry; Reactant concentrations; Reaction temperature; Secondary building units; Solvothermal reactions; Sorption hysteresis; Strong interaction; Threedimensional (3-d)
- Issue Date
- AMER CHEMICAL SOC
- CRYSTAL GROWTH & DESIGN, v.12, no.8, pp.4186 - 4193
- The solvothermal reactions of cobalt(II) chloride hexahydrate and 1,3,5-benzenetribenzoic acid (H3BTB) in anhydrous N,N'-dimethylacetamide (DMA) at two different reaction temperatures and reactant concentrations led to two 3,6-connected metal-organic frameworks (MOFs) with different net topologies based on the ligand as a C-3 symmetric 3-connected organic node and the linear trinuclear cobalt carboxylate cluster, Co-3(COO)(6), as a 6-connected secondary building unit (SBU). MOF [Co-3(BTB)(2)(DMA)(4)], 1, with a linear trinuclear cobalt carboxylate cluster, Co-3(COO)(6), and with an inversion point symmetry with "compressed trigonal antiprismatic" 6-connectivity, is a two-dimensional (2-D) layered structure of a 3,6-connected kgd net topology. However, the same linear trinuclear cobalt carboxylate cluster, Co-3(COO)(6), with a 2-fold point symmetry with "compressed trigonal prismatic" 6-connectivity leads to the three-dimensional (3-D) network of 2, with an unprecedented 3,6-connected net topology with the point symbol (4(3))(2)(4(3).12(12)). The 2-D layered framework, 1, shows a significant sorption hysteresis for adsorbates with relatively strong interactions with the framework, such as N-2 and CO2.
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