A two-fold interpenetrated (3,6)-connected metal-organic framework with rutile topology showing a large solvent cavity
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- A two-fold interpenetrated (3,6)-connected metal-organic framework with rutile topology showing a large solvent cavity
- Song, Xiaokai; Zou, Yang; Liu, Xinfang; Oh, Minhak; Lah, Myoung Soo
- OCTAHEDRAL BUILDING-BLOCKS; RETICULAR CHEMISTRY; PORE-SIZE; DESIGN; NETWORK; LIGAND; ADSORPTION; MOLECULES; UNITS; NETS
- Issue Date
- ROYAL SOC CHEMISTRY
- NEW JOURNAL OF CHEMISTRY, v.34, no.11, pp.2396 - 2399
- A two-fold interpenetrated metal-organic framework (MOF), [(Zn(4)O)(2)L(4)(DMF)(2)(H(2)O)(3)], was prepared using the tritopic ligand 4,4',4 ''-[1,3,5-benzenetriyltris(carbonylimino)]trisbenzoic acid (H(3)L) and zinc nitrate. The MOF, based on the hexatopic tetranuclear Zn(4)O(COO)(6) secondary building unit, has a (3,6)-connected network with an rtl topology and a large solvent cavity.
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