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Cho, Jaephil
Nano Energy Storage Material Lab.
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Cobalt–Tannin-Framework-Derived Amorphous Co−P/Co−N−C on N, P Co-Doped Porous Carbon with Abundant Active Moieties for Efficient Oxygen Reactions and Water Splitting

Author(s)
Wang, ShuaiJang, HaeseongWang, JiaWu, ZexingLiu, XienCho, Jaephil
Issued Date
2019-02
DOI
10.1002/cssc.201802909
URI
https://scholarworks.unist.ac.kr/handle/201301/26277
Fulltext
https://onlinelibrary.wiley.com/doi/full/10.1002/cssc.201802909
Citation
CHEMSUSCHEM, v.12, no.4, pp.830 - 838
Abstract
It remains a tremendous challenge to develop a low-cost, earth-abundant, and efficient catalyst with multifunctional activities for the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR). Herein, a facile and scalable avenue was developed to prepare amorphous Co−P/Co−N−C supported on N, P co-doped porous carbon (Co−P/Co−N−C/NPC) with a large specific surface area (1462.9 m2 g−1) and abundant reactive sites including Co−P, Co−N and NPC. The prepared electrocatalyst exhibits outstanding catalytic performance for HER (η=234 mV at 10 mA cm−2), OER (η=374 mV at 10 mA cm−2), and ORR (E1/2=0.89 V, vs. reversible hydrogen electrode). Benefiting from the excellent HER performance and outstanding OER activity, the Co−P/Co−N−C/NPC delivers a current density of 10 mA cm−2 for overall water splitting at a cell voltage of 1.59 V, which is comparable with the IrO2–Pt/C couple electrode.
Publisher
Wiley-VCH Verlag
ISSN
1864-5631
Keyword (Author)
multifunctional activitiesnon-noble catalystsoxygen reduction reactionporous carbonwater splitting
Keyword
Water splittingAmorphous carbonCatalyst activityCobaltElectrocatalystsElectrodesElectrolytic reductionHydrogenOxygenPorous materialsHydrogen evolution reactionsLarge specific surface areasMultifunctional activityOxygen evolution reactionOxygen reduction reactionPorous carbonsReversible hydrogen electrodes

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