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- Bielawski, Christopher W.
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Design, synthesis and study of a photochromic alpha,omega-diene: toward new classes of photoswitchable polymers
- Author(s)
- Joo, Wontae, Bielawski, Christopher W.
- Issued Date
- 2019-03
- Citation
- ORGANIC & BIOMOLECULAR CHEMISTRY, v.17, no.9, pp.2486 - 2491
- Abstract
- A 4,5-dithienylimidazolium salt outfitted with pendant styrenyl groups was synthesized and studied. The salt was found to undergo reversible electrocyclization upon UV irradiation; subsequent exposure to visible light reversed the reaction. Acyclic diene metathesis (ADMET) polymerization of the salt afforded a novel fluorescent polyelectrolyte.
- Publisher
- ROYAL SOC CHEMISTRY
- ISSN
- 1477-0520
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