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DC Field | Value | Language |
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dc.citation.endPage | 4565 | - |
dc.citation.number | 31 | - |
dc.citation.startPage | 4562 | - |
dc.citation.title | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | - |
dc.citation.volume | 2017 | - |
dc.contributor.author | Some, Surajit | - |
dc.contributor.author | Bae, Han Yong | - |
dc.contributor.author | Kim, Mun Jong | - |
dc.contributor.author | Zhang, Yong Jian | - |
dc.contributor.author | Song, Choong Eui | - |
dc.date.accessioned | 2023-12-21T21:49:37Z | - |
dc.date.available | 2023-12-21T21:49:37Z | - |
dc.date.created | 2019-02-11 | - |
dc.date.issued | 2017-08 | - |
dc.description.abstract | Herein, we report an ultrasound-promoted enantio-selective decarboxylative protonation reaction of alpha-aminomalonate hemiesters 1 in the presence of chiral cinchona-derived squaramide Bronsted bases under mild conditions, which afforded both the (S)- and (R)-enantiomers of alpha-amino acid derivatives 2 in excellent yields (>90 %) and excellent enantioselectivities (up to 98 % ee). | - |
dc.identifier.bibliographicCitation | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2017, no.31, pp.4562 - 4565 | - |
dc.identifier.doi | 10.1002/ejoc.201700786 | - |
dc.identifier.issn | 1434-193X | - |
dc.identifier.scopusid | 2-s2.0-85028091373 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/25868 | - |
dc.identifier.url | https://onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201700786 | - |
dc.identifier.wosid | 000408148700006 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | Ultrasound-Promoted Enantioselective Decarboxylative Protonation of alpha-Aminomalonate Hemiesters by Chiral Squaramides: A Practical Approach to Both Enantiomers of alpha-Amino Esters | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | Ultrasound irradiation | - |
dc.subject.keywordAuthor | Bronsted base catalysis | - |
dc.subject.keywordAuthor | Decarboxylation | - |
dc.subject.keywordAuthor | Amino acids | - |
dc.subject.keywordAuthor | Enantioselectivity | - |
dc.subject.keywordAuthor | Chiral cinchona-based squaramides | - |
dc.subject.keywordPlus | MICHAEL-ADDITION | - |
dc.subject.keywordPlus | ASYMMETRIC-SYNTHESIS | - |
dc.subject.keywordPlus | BETA-NITROOLEFINS | - |
dc.subject.keywordPlus | ACIDS | - |
dc.subject.keywordPlus | ORGANOCATALYSTS | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | NITROALKENES | - |
dc.subject.keywordPlus | RECOGNITION | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.subject.keywordPlus | CENTERS | - |
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