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- Bae, Han Yong
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Hydrogen bonding mediated enantioselective organocatalysis in brine: significant rate acceleration and enhanced stereoselectivity in enantioselective Michael addition reactions of 1,3-dicarbonyls to beta-nitroolefins
- Author(s)
- Bae, Han Yong, Some, Surajit, Oh, Joong Suk, Lee, Yong Seop, Song, Choong Eui
- Issued Date
- 2011-09
- Citation
- CHEMICAL COMMUNICATIONS, v.47, no.34, pp.9621 - 9623
- Abstract
- Brine provides remarkable rate acceleration and a higher level of stereoselectivity over organic solvents, due to the hydrophobic hydration effect, in the enantioselective Michael addition reactions of 1,3-dicarbonyls to beta-nitroolefins using chiral H-donors as organocatalysts.
- Publisher
- ROYAL SOC CHEMISTRY
- ISSN
- 1359-7345
- Keyword
- WATER, DERIVATIVES
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