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Moon, Hoi Ri
Functional Inorganic Nanomaterials for Energy Lab (FINE)
Research Interests
  • Inorganic-organic hybrid materials, carbon capture materials, hydrogen storage materials, heterogeneous catalyst

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Structural diversity of metal-organic frameworks via employment of azamacrocycles as a building block

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Title
Structural diversity of metal-organic frameworks via employment of azamacrocycles as a building block
Author
Lee, Jae HwaMoon, Hoi Ri
Issue Date
2018-12
Publisher
SPRINGER
Citation
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, v.92, no.3-4, pp.237 - 249
Abstract
Research on incorporating macrocycles into metal-organic frameworks (MOFs) has been performed intensively due to the opportunities afforded by merging a merit of macrocycles with MOF chemistry, which lead to novel hybrid materials for potential application. Among the numerous kinds of macrocycles, azamacrocycles are used as traditional and popular chelating agents in supramolecular coordination chemistry, because they are very easily functionalized by joining pendant arms and possess a strong propensity to complex metal cations, accounting for the amine functionalities. With this as background, many types of azamacrocyclic MOFs have been synthesized, granting compositionally and topologically new MOFs. The macrocyclic rings can serve as additional adsorption sites or catalytic sites, and the pendant arms on the macrocycles can also play versatile roles such as structure-directing agents, pore-decorating moieties, or rotatable molecular gates for opening/closing pores. In this review, we comprehensively discuss the syntheses, structures, and features of azamacrocyclic MOFs reported to date. Based on representative studies, advantages of these compounds are described, such as how the azamacrocycles increase the structural diversity and complexity of the MOFs and induce novel structural properties within the architectures.
URI
https://scholarworks.unist.ac.kr/handle/201301/25425
URL
https://link.springer.com/article/10.1007%2Fs10847-018-0855-4
DOI
10.1007/s10847-018-0855-4
ISSN
1388-3127
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PHY_Journal Papers
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