There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 14768 | - |
dc.citation.number | 30 | - |
dc.citation.startPage | 14761 | - |
dc.citation.title | JOURNAL OF MATERIALS CHEMISTRY A | - |
dc.citation.volume | 6 | - |
dc.contributor.author | Shin, Dong-Seon | - |
dc.contributor.author | Park, Minjoon | - |
dc.contributor.author | Ryu, Jaechan | - |
dc.contributor.author | Hwang, Inchan | - |
dc.contributor.author | Seo, Jeong Kon | - |
dc.contributor.author | Seo, Kwanyong | - |
dc.contributor.author | Cho, Jaephil | - |
dc.contributor.author | Hong, Sung You | - |
dc.date.accessioned | 2023-12-21T20:20:48Z | - |
dc.date.available | 2023-12-21T20:20:48Z | - |
dc.date.created | 2018-08-02 | - |
dc.date.issued | 2018-08 | - |
dc.description.abstract | Chemically modified organic redox couples have the advantages of tunable redox properties, high solubility, environmental benignity, and cost effectiveness. Inspired by nature, a series of quinone derivatives bearing electron-donating methoxy or electron-withdrawing trifluoromethyl groups are synthesized in moderate to high yields by Pd-catalyzed Suzuki cross-coupling reactions. This study utilizes the synthetic quinones as redox-active organic molecules for nonaqueous lithium-organic flow batteries. The aryl moiety incorporated quinone scaffolds show enhanced electrochemical stability and rate capability. The nonaqueous catholyte, 2-phenyl-1,4-naphthoquinone, reaches a cell voltage of similar to 2.6 V and a specific capacity of 196 mA h g(-1), while the discharge capacity is retained at similar to 92% for 150 cycles. Moreover, the tubular lithium-organic flow battery system features stable cycle performance under a continuous circulation without clogging-associated intermittency flow. | - |
dc.identifier.bibliographicCitation | JOURNAL OF MATERIALS CHEMISTRY A, v.6, no.30, pp.14761 - 14768 | - |
dc.identifier.doi | 10.1039/C8TA04720K | - |
dc.identifier.issn | 2050-7488 | - |
dc.identifier.scopusid | 2-s2.0-85051008770 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/24671 | - |
dc.identifier.url | http://pubs.rsc.org/en/content/articlelanding/2018/ta/c8ta04720k#!divAbstract | - |
dc.identifier.wosid | 000443117300028 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Nonaqueous arylated quinone catholytes for lithium-organic flow batteries | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Energy & Fuels; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry; Energy & Fuels; Materials Science | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | HIGH-ENERGY | - |
dc.subject.keywordPlus | RECHARGEABLE BATTERIES | - |
dc.subject.keywordPlus | LI-ION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | ELECTROLYTES | - |
dc.subject.keywordPlus | CAPACITY | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordPlus | TEREPHTHALATE | - |
dc.subject.keywordPlus | PD(OAC)(2) | - |
dc.subject.keywordPlus | CHALLENGES | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.