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Moon, Hoi Ri
Functional Inorganic Nanomaterials Lab for Energy
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Three-dimensional iron(II) porous coordination polymer exhibiting carbon dioxide-dependent spin crossover

Author(s)
Shin, Jong WonJeong, Ah RimJeoung, SungeunMoon, Hoi RiKomatsumaru, YukiHayami, ShinyaMoon, DohyunMin, Kil Sik
Issued Date
2018-04
DOI
10.1039/c8cc00678d
URI
https://scholarworks.unist.ac.kr/handle/201301/24151
Fulltext
http://pubs.rsc.org/en/Content/ArticleLanding/2018/CC/C8CC00678D#!divAbstract
Citation
CHEMICAL COMMUNICATIONS, v.54, no.34, pp.4262 - 4265
Abstract
We report a three-dimensional Fe(II) porous coordination polymer that exhibits a spin crossover temperature change following CO2 sorption (though not N-2 sorption). Furthermore, single crystals of the desolvated polymer with CO2 molecules at three different temperatures were characterised by X-ray crystallography.
Publisher
ROYAL SOC CHEMISTRY
ISSN
1359-7345
Keyword
METAL-ORGANIC FRAMEWORKSSINGLE-MOLECULE-MAGNETCO2 SORPTIONADSORPTIONTRANSITIONMECHANISMBEHAVIORCRYSTALCAPTURENETWORK

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