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Park, Cheol-Min
Synthetic & Medicinal Chemistry Lab
Research Interests
  • Organic synthesis, medicinal chemistry, chemical biology


A catalyst-controlled selective synthesis of pyridines and pyrroles

DC Field Value Language Jiang, Yaojia ko Park, Cheol-Min ko 2014-04-09T07:58:35Z - 2014-03-10 ko 2014-06 ko
dc.identifier.citation CHEMICAL SCIENCE, v.5, no.6, pp.2347 - 2351 ko
dc.identifier.issn 2041-6520 ko
dc.identifier.uri -
dc.description.abstract We have developed a dual reaction manifold that enables selective synthesis of both pyridines and pyrroles from common substrates α-diazo oxime ethers. The strong propensity of 1,3-dienyl nitrenes for 4π-electrocyclization to give pyrroles could be diverted to 6π-electrocyclization via 1,6-hydride shift or prototropic isomerization leading to exclusive formation of pyridines by employing metal nitrene complexes derived from α-diazo oxime ethers under Rh(II) catalysis. Furthermore, an orthogonal catalytic system has been identified that promotes selective formation of 1H-pyrroles from the same substrates by redirecting the reactivity of vinyl 2H-azirine intermediates. ko
dc.description.statementofresponsibility close -
dc.language 영어 ko
dc.publisher ROYAL SOC CHEMISTRY ko
dc.title A catalyst-controlled selective synthesis of pyridines and pyrroles ko
dc.type ARTICLE ko
dc.identifier.scopusid 2-s2.0-84900338682 ko
dc.identifier.wosid 000336254500030 ko
dc.type.rims ART ko
dc.description.wostc 3 *
dc.description.scopustc 1 * 2015-02-28 * 2014-08-26 *
dc.identifier.doi 10.1039/C4SC00125G ko
dc.identifier.url ko
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