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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 2351 | - |
dc.citation.number | 6 | - |
dc.citation.startPage | 2347 | - |
dc.citation.title | CHEMICAL SCIENCE | - |
dc.citation.volume | 5 | - |
dc.contributor.author | Jiang, Yaojia | - |
dc.contributor.author | Park, Cheol-Min | - |
dc.date.accessioned | 2023-12-22T02:39:24Z | - |
dc.date.available | 2023-12-22T02:39:24Z | - |
dc.date.created | 2014-03-10 | - |
dc.date.issued | 2014-06 | - |
dc.description.abstract | We have developed a dual reaction manifold that enables selective synthesis of both pyridines and pyrroles from common substrates α-diazo oxime ethers. The strong propensity of 1,3-dienyl nitrenes for 4π-electrocyclization to give pyrroles could be diverted to 6π-electrocyclization via 1,6-hydride shift or prototropic isomerization leading to exclusive formation of pyridines by employing metal nitrene complexes derived from α-diazo oxime ethers under Rh(II) catalysis. Furthermore, an orthogonal catalytic system has been identified that promotes selective formation of 1H-pyrroles from the same substrates by redirecting the reactivity of vinyl 2H-azirine intermediates. | - |
dc.identifier.bibliographicCitation | CHEMICAL SCIENCE, v.5, no.6, pp.2347 - 2351 | - |
dc.identifier.doi | 10.1039/C4SC00125G | - |
dc.identifier.issn | 2041-6520 | - |
dc.identifier.scopusid | 2-s2.0-84900338682 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/2412 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84900338682 | - |
dc.identifier.wosid | 000336254500030 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | A catalyst-controlled selective synthesis of pyridines and pyrroles | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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