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김재업

Kim, Jaeup U.
Nanostructured Polymer Theory Lab.
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Laser-Directed Self-Assembly of Highly Aligned Lamellar and Cylindrical Block Copolymer Nanostructures: Experiment and Simulation

Author(s)
Yong, DaeseongJin, Hyeong MinKim, Sang OukKim, Jaeup U.
Issued Date
2018-02
DOI
10.1021/acs.macromol.7b02645
URI
https://scholarworks.unist.ac.kr/handle/201301/23217
Fulltext
https://pubs.acs.org/doi/10.1021/acs.macromol.7b02645
Citation
MACROMOLECULES, v.51, no.4, pp.1418 - 1426
Abstract
Laser photothermal annealing is emerging as a promising strategy for directed self-assembly of block copolymers along with its unique advantages, such as area selectivity, solvent-free ultrafast process, and highly oriented nanopattern formation without substrate prepatterning. We investigate laser-induced highly aligned lamellar and cylindrical self-assembled nanostructure formation by means of simulation as well as experiment. Self-assembled surface-perpendicular lamellar or surface-parallel cylindrical nanodomains in PS-b-PMMA thin films could be aligned by lateral steady scan of focused laser irradiation to attain excellent long-range order over 10 μm length scale. For the systematic understanding of the experimental observation, quasi-static simulation employing successive self-consistent field theory calculation has been developed. Miniaturized simulations of experimental systems could confirm a strong tendency for lamellar domains to grow in the direction of laser scanning. Cylindrical self-assembled domains exhibit similar behaviors provided that the surface prefers one block and the block copolymer film thickness is moderate.
Publisher
AMER CHEMICAL SOC
ISSN
0024-9297
Keyword
ORDER-DISORDER TRANSITIONSINGLE-LAYER FILMSDIBLOCK COPOLYMERSTHIN-FILMSMICRODOMAIN ORIENTATIONMICROPHASE SEPARATIONALIGNMENTGRAPHOEPITAXYTEMPERATURECYLINDERS

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