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DC Field | Value | Language |
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dc.citation.endPage | D751 | - |
dc.citation.number | 12 | - |
dc.citation.startPage | D744 | - |
dc.citation.title | JOURNAL OF THE ELECTROCHEMICAL SOCIETY | - |
dc.citation.volume | 164 | - |
dc.contributor.author | Park, Jaeyeong | - |
dc.contributor.author | Choi, Sungyeol | - |
dc.contributor.author | Sohn, Sungjune | - |
dc.contributor.author | Hwang, Il Soon | - |
dc.date.accessioned | 2023-12-21T21:36:44Z | - |
dc.date.available | 2023-12-21T21:36:44Z | - |
dc.date.created | 2017-11-23 | - |
dc.date.issued | 2017-12 | - |
dc.description.abstract | To achieve a better understanding of Zircaloy-4 electrorefining in LiCl-KCl at 500°C, redox behaviors of Zr, Sn, Cr, Fe and Co, were examined by cyclic voltammetry using tungsten working and counter electrode. Zr metal can be produced from Zr4+ through two step reduction and ZrCl is generated as an intermediate product. As ZrCl4 concentration decreases, ZrCl would be easily reduced into Zr metal. In addition, Zr2+ formation would be unlikely at low ZrCl4 concentration. The redox reactions of the other elements are much simpler than Zr. The reduction of Zr4+ into ZrCl was close to irreversible but the reduction reactions of the other elements are close to reversible. The diffusion coefficients and apparent reduction potentials were calculated using equations for a reversible or irreversible reaction. The diffusion coefficients are in the order of 10−9 m2/s and Zr is less reductive than other elements. | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE ELECTROCHEMICAL SOCIETY, v.164, no.12, pp.D744 - D751 | - |
dc.identifier.doi | 10.1149/2.1501712jes | - |
dc.identifier.issn | 0013-4651 | - |
dc.identifier.scopusid | 2-s2.0-85033404139 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/22961 | - |
dc.identifier.url | http://jes.ecsdl.org/content/164/12/D744.abstract | - |
dc.identifier.wosid | 000415283600115 | - |
dc.language | 영어 | - |
dc.publisher | ELECTROCHEMICAL SOC INC | - |
dc.title | Cyclic Voltammetry on Zr, Sn, Fe, Cr and Co in LiCl-KCl Salts at 500°C for Electrorefining of Irradiated Zircaloy-4 Cladding | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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