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Kim, Yong Hwan
Enzyme and Protein Engineering Lab.
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Enzymatic production of glycerol carbonate from by-product after biodiesel manufacturing process

Author(s)
Jung, HongsubLee, YoungrakKim, DaeheumHan, Sung OkKim, Seung WookLee, JinwonKim, Yong HwanPark, Chulhwan
Issued Date
2012-08
DOI
10.1016/j.enzmictec.2012.05.004
URI
https://scholarworks.unist.ac.kr/handle/201301/20361
Fulltext
http://www.sciencedirect.com/science/article/pii/S0141022912000737
Citation
ENZYME AND MICROBIAL TECHNOLOGY, v.51, no.3, pp.143 - 147
Abstract
Glycerol carbonate is one of the higher value-added products derived from glycerol. In this study, glycerol carbonate (GC) was synthesized by transesterification of glycerol and dimethyl carbonate (DMC) using Novozym 435 (Candida antarctica Lipase B) at various conditions. For the enzymatic production of GC, the optimum conditions were the amount of enzyme (75 g/L), DMC/glycerol molar ratio (2.00), reaction temperature (60 degrees C) and organic solvent (acetonitrile). Experimental investigation of the effect of water content revealed that the conversion of GC was maximized with no added water. The addition of surfactant such as Tween 80 increased the GC conversion, which finally reached 96.25% under the optimum condition and with surfactant addition. (C) 2012 Elsevier Inc. All rights reserved
Publisher
ELSEVIER SCIENCE INC
ISSN
0141-0229
Keyword (Author)
LipaseGlycerolGlycerol carbonateBiodieselValue-added chemical
Keyword
DIMETHYL CARBONATECATALYZED SYNTHESISLIPASETRANSESTERIFICATIONOPTIMIZATIONBIOSYNTHESISCONVERSIONOIL

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