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김용환

Kim, Yong Hwan
Enzyme and Protein Engineering Lab.
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Enzymatic coproduction of biodiesel and glycerol carbonate from soybean oil in solvent-free system

Author(s)
Go, A-RaLee, YoungrakKim, Young HwanPark, SehkyuChoi, JoongsoLee, JinwonHan, Sung OkKim, Seung WookPark, Chulhwan
Issued Date
2013-08
DOI
10.1016/j.enzmictec.2013.02.016
URI
https://scholarworks.unist.ac.kr/handle/201301/20354
Fulltext
http://www.sciencedirect.com/science/article/pii/S0141022913000380
Citation
ENZYME AND MICROBIAL TECHNOLOGY, v.53, no.3, pp.154 - 158
Abstract
The enzymatic coproduction of biodiesel and glycerol carbonate by transesterification of soybean oil and dimethyl carbonate (DMC) has been studied in a solvent-free system. The effects on biodiesel and glycerol carbonate conversion of reaction conditions including the kind of enzyme, the amount of enzyme, the molar ratio of DMC to soybean oil, the reaction temperature, and water addition were investigated. The optimal conditions for biodiesel and glycerol carbonate were 20% Novozym 435, 10:1 molar ratio of DMC to soybean oil, and 0.7% water addition. Under these conditions, the conversions of 96.4% biodiesel and 92.1% glycerol carbonate have been achieved after 48 h.
Publisher
ELSEVIER SCIENCE INC
ISSN
0141-0229
Keyword (Author)
BiodieselGlycerol carbonateNovozym 435Solvent-free system
Keyword
DIMETHYL CARBONATECATALYZED SYNTHESISIMMOBILIZED-LIPASEFUEL PRODUCTIONVEGETABLE-OILSACYL ACCEPTORORGANIC MEDIAPALM OILTRANSESTERIFICATIONOPTIMIZATION

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