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장지현

Jang, Ji-Hyun
Structures & Sustainable Energy Lab.
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Dendrimer-Capped Gold Nanoparticles for Highly Reliable and Robust Surface Enhanced Raman Scattering

Author(s)
Kim, KwanghyunLee, JeongyeopJo, GyeongcheonShin, SeungminKim, Jin-BaekJang, Ji-Hyun
Issued Date
2016-08
DOI
10.1021/acsami.6b05710
URI
https://scholarworks.unist.ac.kr/handle/201301/20303
Fulltext
http://pubs.acs.org/doi/abs/10.1021/acsami.6b05710
Citation
ACS APPLIED MATERIALS & INTERFACES, v.8, no.31, pp.20379 - 20384
Abstract
Dendrimer-stabilized gold nanoparticles (Au-Den) were prepared by a facile solution based method for a highly reliable and robust surface enhanced Raman scattering (SERS) substrate. Au-Den was selectively attached on the surface of reduced graphene oxide (rGO) by noncovalent interactions between the Au capping dendrimer and the graphene surface. Au-Den/rGO exhibits the outstandingly stable and highly magnified Raman signal with an enhancement factor (EF) of 3.9 X 10(7) that enables detection of R6G dyes with concentration as low as 10 nM, retaining 95% of the Raman signal intensity after 1 year. The remarkable stability and enhancement originated not only from a simple combination of the electromagnetic and chemical mechanism of SERS but also from intensified packing density of stable Au Den on the graphene substrate due to the firm binding between the dendrimer capped metal nanoparticles and the graphene substrate. This method is not limited to the gold nanoparticles and G4 dendrimer used herein, but also can be applied to other dendrimers and metal nanoparticles, which makes the material platform suggested here superior to other SERS substrates.
Publisher
American Chemical Society
ISSN
1944-8244
Keyword (Author)
SERSGERSgold nanoparticlereduced graphene oxidedendrimer (PAMAM-G4)stability
Keyword
REDUCED GRAPHENE OXIDEPOLYMER SOLAR-CELLSSILVER ELECTRODEENCAPSULATED NANOPARTICLESSERSSPECTROSCOPYSUBSTRATEMICROSCOPYMOLECULESPYRIDINE

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