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Park, Soojin
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Organogel electrolyte for high-loading silicon batteries

Author(s)
Cho, Yoon-GyoPark, HyungminLee, Jung-InHwang, ChihyunJeon, YujuPark, SoojinSong, Hyun-Kon
Issued Date
2016-05
DOI
10.1039/C6TA02341J
URI
https://scholarworks.unist.ac.kr/handle/201301/19222
Fulltext
http://pubs.rsc.org/en/content/articlelanding/2016/ta/c6ta02341j#!divAbstract
Citation
JOURNAL OF MATERIALS CHEMISTRY A, v.4, no.21, pp.8005 - 8009
Abstract
A cyanoresin organogel electrolyte, characterized by in situ gelation with no initiators or crosslinkers, was used for high-loading silicon batteries of 1.3 mg(si) cm(-2) (equivalent to 3.3 mA h cm(-2)). The organogel provided additional cohesion between the silicon particles and maintained electrode integrity even after pulverization, completely suppressing severe crack development and serious electrode thickness changes observed in liquid electrolytes. The capacity retention upon cycling was significantly improved in the organogel when compared with its liquid counterpart.
Publisher
ROYAL SOC CHEMISTRYROYAL SOC CHEMISTRY
ISSN
2050-7488
Keyword
LITHIUM-ION BATTERIESVOLUME-CHANGEANODESCHALLENGESCELLS

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