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- Bielawski, Christopher W.
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A cyclic (alkyl)(amido)carbene: synthesis, study and utility as a desulfurization reagent
- Issued Date
- 2016-04
- Citation
- CHEMICAL COMMUNICATIONS, v.52, no.31, pp.5447 - 5450
- Abstract
- The synthesis and study of a cyclic (alkyl)(amido) carbene is described. The carbene was found to undergo C-H insertion at low temperatures, formed cyclopropenes upon exposure to alkynes, and facilitated desulfurization reactions. Spectroscopic studies revealed that the carbene is strongly pi-accepting but retains a complimentary degree of sigma-donating properties.
- Publisher
- ROYAL SOC CHEMISTRY
- ISSN
- 1359-7345
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