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- Choe, Wonyoung
- Laboratory for Sustainable Future
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Pillared Porphyrin Homologous Series: Intergrowth in Metal-Organic Frameworks
- Author(s)
- Choe, Wonyoung, Choi, Eun-Young, Paul M. Barron, Richard W. Novotny, Chunhua Hu
- Issued Date
- 2008-12
- Citation
- INORGANIC CHEMISTRY, v.48, no.2, pp.426 - 428
- Abstract
- We report three new porphyrin-based, pillared paddle-wheel homologous series: porphyrin paddle-wheel frameworks PPF-3, -4, and -5. These compounds are assembled from free base or palladium tetrakis(4-carboxyphenyl)porphine, M(NO(3))(2) (M = Co and Zn), and 4,4'-bipyridine via solvothermal reactions. The resulting solids exhibit 3D metal-organic frameworks, where 2D layers are pillared by bipyridine with three different packing arrangements.
- Publisher
- AMER CHEMICAL SOC
- ISSN
- 0020-1669
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