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- Kang, Seok Ju
- Smart Materials for Energy Lab.
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6,12-Diarylindeno[1,2-b]fluorenes: Syntheses, Photophysics, and Ambipolar OFETs
- Author(s)
- Chase, Daniel T., Fix, Aaron G., Kang, Seok Ju, Rose, Bradley D., Weber, Christopher D., Zhong, Yu, Zakharov, Lev N., Lonergan, Mark C., Nuckolls, Colin, Haley, Michael M.
- Issued Date
- 2012-06
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.134, no.25, pp.10349 - 10352
- Abstract
- Herein we report the synthesis and characterization of a series of 6,12-diarylindeno[1,2-b]fluorenes (IFs). Functionalization with electron donor and acceptor groups influences the ability of the IF scaffold to undergo two-electron oxidation and reduction to yield the corresponding 18- and 22-pi-electron species, respectively. A single crystal of the pentafluorophenyl-substituted IF can serve as an active layer in an organic field-effect transistor (OFET). The important finding is that the single-crystal OFET yields an ambipolar device that is able to transport holes and electrons
- Publisher
- AMER CHEMICAL SOC
- ISSN
- 0002-7863
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