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Bielawski, Christopher W.
Synthetic Materials & Macromolecules
Research Interests
  • Synthetic chemistry, materials science, polymer chemistry, catalysis, carbon-based materials

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Post-polymerization modification of poly(vinyl ether)s: A Ru-catalyzed oxidative synthesis of poly(vinyl ester)s and poly(propenyl ester)s

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Title
Post-polymerization modification of poly(vinyl ether)s: A Ru-catalyzed oxidative synthesis of poly(vinyl ester)s and poly(propenyl ester)s
Author
Liu, DiBielawski, Christopher W.
Issue Date
2016-01
Publisher
ROYAL SOC CHEMISTRY
Citation
POLYMER CHEMISTRY, v.7, no.1, pp.63 - 68
Abstract
Poly(vinyl ester)s were readily prepared via a ruthenium catalyzed C-H oxidation of the corresponding poly(vinyl ether)s under mild conditions. The transformations were efficient and in many cases proceeded without significant chain cleavage. The method was also successfully used to prepare high molecular weight poly(propenyl ester) for the first time as well as a polyester with a relatively high content (>50%) of γ-butyrolactone repeat unit from poly(tetrahydrofuran). The polymeric products were characterized via FT-IR spectroscopy, NMR spectroscopy, gel permeation chromatography, and other techniques.
URI
https://scholarworks.unist.ac.kr/handle/201301/18033
URL
http://pubs.rsc.org/en/Content/ArticleLanding/2016/PY/C5PY01409C#!divAbstract
DOI
10.1039/c5py01409c
ISSN
1759-9954
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CHM_Journal Papers
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