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Moon, Hoi Ri
Functional Inorganic Nanomaterials Lab for Energy
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Solvent-induced single-crystal to single-crystal transformation of a Zn4O-containing doubly interpenetrated metal-organic framework with a pcu net

Author(s)
Lee, Jae HwaKim, Tae KyungSuh, a Myunghyun PaikMoon, Hoi Ri
Issued Date
2015-12
DOI
10.1039/c5ce01074h
URI
https://scholarworks.unist.ac.kr/handle/201301/17952
Fulltext
http://pubs.rsc.org/en/Content/ArticleLanding/2015/CE/C5CE01074H#!divAbstract
Citation
CRYSTENGCOMM, v.17, no.46, pp.8807 - 8811
Abstract
Guest molecules in a metal-organic framework (MOF), [Zn4O(CPMA)3]·6DMF (DMF = N,N-dimethylformamide), with an interpenetrating pcu net were exchanged with benzene, n-hexane, and methanol in a single-crystal to single-crystal (SC-SC) manner, which involved the sliding motion of the interpenetrating network, as well as the dynamic movements of the molecular components, and was triggered by host-guest interactions.
Publisher
ROYAL SOC CHEMISTRY
ISSN
1466-8033
Keyword
SITESGAS-SORPTION PROPERTIESBILAYER OPEN FRAMEWORKPI-PI-INTERACTIONSGUEST EXCHANGECOORDINATION POLYMERTEMPERATUREDYNAMICSREMOVALBINDING

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