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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)
  • Crystal Engineering
  • Supramolecular coordination chemistry

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Simple and Efficient Regeneration of MOF-5 and HKUST-1 via Acid-Base Treatment

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Title
Simple and Efficient Regeneration of MOF-5 and HKUST-1 via Acid-Base Treatment
Author
Han, SeungwanLah, Myoung Soo
Issue Date
2015-10
Publisher
AMER CHEMICAL SOC
Citation
CRYSTAL GROWTH & DESIGN, v.15, no.11, pp.5568 - 5572
Abstract
Simple and efficient regeneration of MOF-5 and HKUST-1 is demonstrated via add base treatment. The reactants are recovered simply by dissolving the deteriorated MOFs in strong acid. Pristine MOFs are regenerated in high yields by adjusting the solution pH via either in situ base formation or ex situ base addition. Both regeneration protocols are environmentally benign and cost-effective because the reactants in the deteriorated MOFs are recycled. Especially the ex situ base addition protocol can be done in a cheap and environmentally friendly ethanol/water mixed solvent at ambient condition and is suitable for large-scale batch regeneration owing to the simple procedure and short reaction time.
URI
https://scholarworks.unist.ac.kr/handle/201301/17894
URL
http://pubs.acs.org/doi/10.1021/acs.cgd.5b01218
DOI
10.1021/acs.cgd.5b01218
ISSN
1528-7483
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PHY_Journal Papers
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