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최남순

Choi, Nam-Soon
Energy Materials Lab.
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A combination of lithium difluorophosphate and vinylene carbonate as reducible additives to improve cycling performance of graphite electrodes at high rates

Author(s)
Kim, Ko-EunJang, Jun YeongPark, InbokWoo, Myung-HeuiJeong, Myung-HwanShin, Woo CheolUe, MakotoChoi, Nam-Soon
Issued Date
2015-12
DOI
10.1016/j.elecom.2015.10.013
URI
https://scholarworks.unist.ac.kr/handle/201301/17883
Fulltext
http://www.sciencedirect.com/science/article/pii/S1388248115002945
Citation
ELECTROCHEMISTRY COMMUNICATIONS, v.61, pp.121 - 124
Abstract
Lithium difluorophosphate (LiDFP) as a reducible additive is employed to overcome the unsatisfactory rate capability and cycling instability of highly pressed graphite electrodes with high mass loading (8.1 mg/cm2) with a vinylene carbonate (VC)-derived surface film that hampers the charge transport at the graphite-electrolyte interface at high rates. Our investigation reveals that LiDFP modifies the surface chemistry induced by VC and makes a more ionically conductive surface film on graphite, ensuring good rate capability.
Publisher
ELSEVIER SCIENCE INC
ISSN
1388-2481
Keyword (Author)
AdditiveAnodeElectrolyteGraphiteLithium-ion battery
Keyword
RATE CAPABILITYANODESULTONECELLSLI-ION BATTERIES

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