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Choi, Nam-Soon
Energy Materials Lab
Research Interests
  • Rechargeable lithium battery, electrolytes for next generation Mg and Na battery

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Vinylene carbonate and tris(trimethylsilyl) phosphite hybrid additives to improve the electrochemical performance of spinel lithium manganese oxide/graphite cells at 60 degrees C

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Title
Vinylene carbonate and tris(trimethylsilyl) phosphite hybrid additives to improve the electrochemical performance of spinel lithium manganese oxide/graphite cells at 60 degrees C
Author
Koo, BonjaeLee, JeongminLee, YongwonKim, Jun KiChoi, Nam-Soon
Issue Date
2015-08
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Citation
ELECTROCHIMICA ACTA, v.173, pp.750 - 756
Abstract
The organophosphorus compounds tris(trimethylsilyl) phosphite (TMSP) and vinylene carbonate (VC) have been considered for use as functional additives to improve the electrochemical performance of Li1.1Mn1.86Mg0.04O4 (LMO)/graphite full cells. Our investigation reveals that the combination of VC and TMSP as additives enhances the cycling properties and storage performance of full cells at 60 degrees C. The unique functions of the TMSP additive in the VC electrolyte are investigated via ex situ X-ray photoelectron spectroscopy (XPS) and F-19 nuclear magnetic resonance (NMR) measurements. The TMSP additive effectively eliminates trace water and hydrogen fluoride (HF) and produces a protective film on the LMO cathode that alleviates manganese dissolution at 60 degrees C. (C) 2015 Elsevier Ltd. All rights reserved
URI
https://scholarworks.unist.ac.kr/handle/201301/17051
URL
http://www.sciencedirect.com/science/article/pii/S001346861501292X
DOI
10.1016/j.electacta.2015.05.129
ISSN
0013-4686
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