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Kee, Jung-Min
Bioorganic and Chembio Lab
Research Interests
  • Chemical biology, organic synthesis, peptide chemistry, synthetic protein chemistry

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Studies on oxidopyrylium [5+2] cycloadditions: Toward a general synthetic route to the C12-hydroxy daphnetoxins

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Title
Studies on oxidopyrylium [5+2] cycloadditions: Toward a general synthetic route to the C12-hydroxy daphnetoxins
Other Titles
Studies on oxidopyrylium [5+2] cycloadditions: Toward a general syntheti c route to the C12-hydroxy daphnetoxins
Author
Wender, Paul A.Bi, F. ChristopherBuschmann, NicoleGosselin, FrancisKan, CindyKee, Jung-MinOhmura, Hirofumi
Issue Date
2006-11
Publisher
AMER CHEMICAL SOC
Citation
ORGANIC LETTERS, v.8, no.23, pp.5373 - 5376
Abstract
[GRAPHICS] 12-Hydroxydaphnetoxins, members of the structurally fascinating daphnane diterpene family, exhibit a wide range of significant biological activities. A general route to the BC-ring system of 12-hydroxy daphnetoxins is reported based on D-ribose. Depending on the choice of protecting groups and solvent, the oxidopyrylium-alkene [5+2] cycloaddition originating from A provides cycloadduct diastereomer B or C with good to excellent selectivity
URI
https://scholarworks.unist.ac.kr/handle/201301/13351
URL
http://pubs.acs.org/doi/abs/10.1021/ol062234e
DOI
10.1021/ol062234e
ISSN
1523-7060
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CHM_Journal Papers
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