BROWSE

Related Researcher

Author's Photo

Rohde, Jan-Uwe
Transition Metal Chemistry
Research Interests
  • Inorganic chemistry, coordination chemistry, organometallic chemistry, chemical synthesis, catalysis, green chemistry, inorganic reaction mechanisms.

ITEM VIEW & DOWNLOAD

Synthesis and Crystal Structures of the Bis(oxalato)metallates trans-K3[RhCl2(C2O4)2] · 4 H2O and cis-K3[IrCl2(C2O4)2] · H2O

Cited 0 times inthomson ciCited 0 times inthomson ci
Title
Synthesis and Crystal Structures of the Bis(oxalato)metallates trans-K3[RhCl2(C2O4)2] · 4 H2O and cis-K3[IrCl2(C2O4)2] · H2O
Author
Rohde, Jan-UwePreetz, W
Issue Date
2000-06
Publisher
VERLAG Z NATURFORSCH
Citation
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, v.55, no.6, pp.473 - 478
Abstract
By treatment of RhCl3 or IrCl3 with K2C2O4 the bis(oxalato)metallates trans-K3[RhCl2(C2O4)2] and cis-K3[IrCl2(C2O4)2] are formed. From the aqueous solutions single crystals were grown by slow diffusion of ethanol and X-ray structure determinations of trans-K3[RhCl2(C2O4)2] · 4 H2O (monoclinic, space group I2/m, a = 6.218(1), b = 11.837(2), c - 10.357(2) Å, β = 95.55(3)°, Z = 2) and cis-K3[IrCl2(C2O4)2] · H2O (monoclinic, space group /2/a, a = 14.060(3), b = 7.586(2), c = 23.488(5) Å, β = 90.44(3)°, Z = 8) have been performed. The oxalato and chloro ligands of the complex anions are connected via hydrogen bonds and electrostatic interactions to water molecules and potassium ions. The potassium ions are eightfold and in one case ninefold coordinated.
URI
https://scholarworks.unist.ac.kr/handle/201301/13267
DOI
10.1515/znb-2000-0605
ISSN
0932-0776
Appears in Collections:
PHY_Journal Papers
Files in This Item:
There are no files associated with this item.

find_unist can give you direct access to the published full text of this article. (UNISTARs only)

Show full item record

qrcode

  • mendeley

    citeulike

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

MENU