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Lee, Jae Sung
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RHODIUM-CATALYZED CARBONYLATION OF METHYL GLYCOLATE AND GLYCOLIC ACID

Alternative Title
RHODIUM-CATALYZED CARBONYLATION OF METHYL GLYCOLATE AND GLYCOLIC ACID
Author(s)
Lee, Jae SungKIM, Eung JoLEE, Sang HoPARK, Kwang Ho
Issued Date
1991-01
DOI
10.1007/BF02697698
URI
https://scholarworks.unist.ac.kr/handle/201301/13036
Fulltext
http://link.springer.com/article/10.1007%2FBF02697698
Citation
KOREAN JOURNAL OF CHEMICAL ENGINEERING, v.8, no.1, pp.53 - 55
Abstract
Catalytic carbonylation of methyl glycolate in the presence of a homogeneous Rh complex and an iodide promoter yields acetoxy methyl acetate and acetic acid. Carbonylation of glycolic acid under the same conditions gives acetic acid and CO2, probably from decomposition of the malonic acid intermediate
Publisher
KOREAN INSTITUTE CHEMICAL ENGINEERS
ISSN
0256-1115

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