BROWSE

Related Researcher

Author's Photo

Lee, Jae Sung
Eco-friendly Catalysis and Energy Lab
Research Interests
  • Photocatalytic water splitting, artificial photosynthesis, fuel cells, heterogeneous catalysis

ITEM VIEW & DOWNLOAD

STOICHIOMETRY OF PALLADIUM-CATALYZED N,N'-DIPHENYLUREA SYNTHESIS FROM NITROBENZENE, ANILINE AND CARBON-MONOXIDE

Cited 25 times inthomson ciCited 4 times inthomson ci
Title
STOICHIOMETRY OF PALLADIUM-CATALYZED N,N'-DIPHENYLUREA SYNTHESIS FROM NITROBENZENE, ANILINE AND CARBON-MONOXIDE
Other Titles
STOICHIOMETRY OF PALLADIUM-CATALYZED N,N'-DIPHENYLUREA SYNTHESIS FROM NITROBENZENE, ANILINE AND CARBON-MONOXIDE
Author
LEE, Sang MooCHO, Nag SugKIM, Kye DuckOH, Jae SeungLEE, Chul WooLee, Jae Sung
Keywords
AMINES
Issue Date
1992-04
Publisher
Elsevier BV
Citation
JOURNAL OF MOLECULAR CATALYSIS, v.73, no.1, pp.43 - 49
Abstract
By using deuterated nitrobenzene as a reactant, it was found that Pd-catalyzed synthesis of N,N'-diphenylurea from nitrobenzene, aniline and CO proceeded via two parallel routes: (i) PhNO2+PhNH2+3CO-->PhNHCONHPh+2CO2, and (ii) PhNO2+5PhNH2+3CO -->3PhNHCONHPh+2H2O. The relative importance of these two routes depended strongly on the ratio of aniline to nitrobenzene initially fed to the reactor. Mechanisms are proposed that account for these reaction stoichiometries
URI
Go to Link
DOI
10.1016/0304-5102(92)80060-T
ISSN
0304-5102
Appears in Collections:
ECHE_Journal Papers
Files in This Item:
1-s2.0-030451029280060T-main.pdf Download

find_unist can give you direct access to the published full text of this article. (UNISTARs only)

Show full item record

qrcode

  • mendeley

    citeulike

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

MENU