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Lee, Jae Sung
Eco-friendly Catalysis and Energy Lab
Research Interests
  • Photocatalytic water splitting, artificial photosynthesis, fuel cells, heterogeneous catalysis

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XAFS characterization of supported PdCl2-CuCl2 catalysts for co oxidation

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Title
XAFS characterization of supported PdCl2-CuCl2 catalysts for co oxidation
Other Titles
XAFS characterization of supported PdCl2-CuCl2 catalysts for co oxidation
Author
Choi, Sun HeeLee, Jae Sung
Keywords
PdCl2-CuCl2; CO oxidation; XAFS
Issue Date
1996-03
Publisher
Akademiai Kiado
Citation
REACTION KINETICS AND CATALYSIS LETTERS, v.57, no.2, pp.227 - 236
Abstract
A heterogenized Wacker catalyst system in which pores of a high surface area alumina were filled with an aqueous solution of PdCl2-CuCl2 was active for the oxidation of CO near room temperature. The structure of the catalyst was studied by XRD and XAFS. The active phase of Pd was a molecular Pd species whose structure was similar to PdCl2, probably modified by a carbonyl ligand. The active phase of copper was found to be solid Cu2Cl(OH)(3) particles. The presence of Cu was essential to keep the Pd in the Pd(II) state during the reaction
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DOI
10.1007/BF02064737
ISSN
0133-1736
Appears in Collections:
ECHE_Journal Papers
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