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Lee, Jae Sung
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Nanocrystalline WO3 film with high photo-electrochemical activity prepared by polymer-assisted direct deposition

Alternative Title
Nanocrystalline WO3 film with high photo-electrochemical activity prepared by polymer-assisted direct deposition
Author(s)
Hong, Suk JoonJun, HwichanLee, Jae Sung
Issued Date
2010-10
DOI
10.1016/j.scriptamat.2010.05.021
URI
https://scholarworks.unist.ac.kr/handle/201301/12841
Fulltext
http://www.sciencedirect.com/science/article/pii/S1359646210003465
Citation
SCRIPTA MATERIALIA, v.63, no.7, pp.757 - 760
Abstract
Highly photoactive, nanocrystalline WO3 films were fabricated by an economic solution process based on polymer-assisted direct deposition. The optimized film exhibited a photocurrent of 2.3 mA cm(-2) (at 1.23 V vs. reversible hydrogen electrode) under simulated solar illumination (air mass 1.5 global) and a maximum incident photon to current efficiency of 71% at an incident wavelength of 340 nm. The observed performance represents one of the highest values reported for WO3. High crystallinity, porosity and optimum thickness of nanocrystalline films were identified as the critical variables that induce the high photoactivity. (C) 2010 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
ISSN
1359-6462

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